By Owen W. Webster (auth.)
"In precis, New man made equipment is well-referenced and well-written with accomplished descriptions of the 4 topic parts provided. not just is the ebook compatible for the polymer scientist however it additionally offers compatible history studying to chemists of all disciplines."
A. Blencowe and W. Hayes
From: Polymer foreign Society of Chemical undefined, Vol. fifty four, p. 614-615 (2005)
From the reviews:
"...This textual content offers an exceptional creation to every of the mentioned themes in addition to delivering an up to date assessment of the present our bodies of labor whereas highlighting components that also require examine if you are operating in the field." (Alaa S. Abd-El-Aziz, POLYMER NEWS,Vol.30, No.4)
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Sample text
Dendritic Macromolecules Comprising Dithiafulvene Units Polyrotaxane Systems . . . . . . . . . . . . . Conjugated Polymers with Thioketene Dimer Unit . . . 2 Summary and Outlook . . . . . . . . . . . . . . 102 .... . . . . . . 90 . 94 . 96 . 100 References . . . . . . . . . . . . . . . . . . . . 103 1 Introduction A dithiafulvene (1) can form a 1,3-dithiolium cation by an easy one-electron oxidation, as a result of its electron-donating property.
Progress in synthetic chemistry of the dithiafulvene derivatives during the past decade has allowed the preparation of new conjugated polymeric donor systems, in particular, the donor units incorporated in the conjugated main-chain systems. Fully conjugated ribbon structure polymers with TTF unit (4, 5) were prepared by Müllen and coworkers [64, 65]. Although 5 showed poor solubility owing to its rigid structure, 4 was soluble in common organic solvents such as dichloromethane and THF. Different approach via processable precursor polymers gave 4 and 5 effectively.
The relatively low conductivities of 10, compared with those of other TTF polymers, may result from amorphous structures of 10. The oxidation of di(benzylidene)tetrathiapentalenes in CV resulted in the stepwise formation of linearly extended TTF polymers (11) (Scheme 2) [68, 86 Takashi Uemura et al. 69]. The polymerizations involved as a first step the formation of the monomer radical cations which underwent rapidly radical dimerization reactions to produce dicationic protonated TTF derivatives.