By John W. Root (Eds.)
content material: simple response kinetics of fluorine atoms, FO, and NF unfastened radicals / E.H. Appelman and M.A.A. Clyne --
Reactions of radioactive ¹⁸F with alkenes, alkynes, and different substrates / F.S. Rowland, Fleet Rust, and Joan P. Frank --
Radiotracer reviews of thermal hydrogen abstraction reactions by way of atomic fluorine / Siu-Hong Mo, Edward R. provide, Frank E. Little, Ronald G. Manning, Chester A. Mathis, Gerald S. Werre, and John W. Root --
Kinetics and mechanism of the addition of fluorine-containing radicals to olefins / J.M. Tedder and J.C. Walton --
Kinetics and mechanisms of reactions of CF, CHF, and CF₂ radicals / David S.Y. Hsu, M.E. Umstead, and M.C. Lin --
Ion-molecule reactions concerning fluorine-containing natural compounds / Sharon G. Lias --
Crossed molecular beam stories of fluorine chemistry / J.M. Farrar and Y.T. Lee --
Molecular beam stories with F ions / Walter S. Koski --
power disposal in reactions of fluorine atoms with polyatomic hydride molecules as studied through infrared chemiluminescence / Denis Bogan and D.W. Setser --
strength power surfaces for fluorine-hydrogen structures / Charles F. Bender and Henry F. Schaefer, III --
Thermochemistry of fluorocarbon radicals / Alan S. Rodgers --
Chemistry of excessive strength atomic fluorine : regular nation kinetic idea version calculations for the ¹⁸F + H₂ response III / Edward R. supply, Da-Fei Feng, Joel Keizer, Kathleen D. Knierim, and John W. Root --
Electron spin resonance experiences of fluorine-containing radicals in unmarried natural crystals / Lowell D. Kispert --
ESR spectra and constitution of inorganic fluorine-containing unfastened radicals 1 / J.R. Morton and K.F. Preston.
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Additional info for Fluorine-Containing Free Radicals. Kinetics and Dynamics of Reactions
Example text
05 F mixed together ;(b) Reactions of thermal 0 -20 +27 - 5 +40 0 -21 +52 - 7 ΔΗ, kcal/mole -17 0 + 2 0 - 5 + 9 0 +18 - 3 +38 0 +13 F alone. <0. 03 <0. 1 <0. 01 ~0. 02 ~0. 05 6 SF /olefin 0. 01 0. 12 <0. 02 <0. 01 <0. 2 <0. 05 0. 01 <0. 01 <0. 01 <0. 01 ~0. 05 ( b ) Table II. Energetics and Yields for Decomposition Pathways for Fluor ο ethyl Radicals Formed by Addition of F to Olefins (6). ; ACS Symposium Series; American Chemical Society: Washington, DC, 1978. 7 S C H F + H ethylene
R . D . A . Contract No. AT(04-3)-34, Project Agreement No. 126. Literature Cited 1. ,Knox 2. , 3. , Wagner, H. G. Chem. (1970), 74, 585. 4. M. Kinet. Catal. (1970),11,669. 5. Chem. (1970), 74, 3464. 6. Soc. (1972), 94, 1041. 7. , ibid. (1972), 94, 1047. 8. D. Thesis, University of California, Irvine, 1974. This thesis, entitled "Hot and Thermal Reactions of Atomic F in the Gas Phase", contains the most complete description of F recoil chemistry as practiced by Rowland and coworkers. 9. 1, International Atomic Energy Agency, Vienna, 1965,p149.
Kinet. (1975), 8, 81. 33. Phys. (1971), 55, 2690. 34. , Disc. (1973), 55, 344. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1978. 58 FLUORINE-CONTAINING FREE RADICALS 35. Phys. (1972), 56, 4658. 36. Soc. (1970), 92, 1311. 37. , later improved unpublished results; see references cited in (12). 38. , Advan. Photochem. (1963), 1, 157. 39. , unpublished results. 40. , J. Phys. (1960), 33, 1271. 41. , Parsonage on Gas Phase Additio 1972,p12. 42. , (1957),2800. 43. Soc. (1974), 96, 1370.