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Soc. Rev. Vol. 39 (2010), 228 [15] Y. Shao, J. Wang, H. Wu, J. Liu, I. Aksay and Y. Lin: Electroanalysis Vol. 22 (2010), p. 1027 [16] W. Yang, K. Ratinac, S. Ringer, P. Thordarson, J. Gooding and F. Braet: Angew. Chem. Int. Ed. Vol. 49 (2010), p. 2114 [17] M. Dresselhau, A. Jorio, M. Hofmann, G. Dresselhaus and R. Saito: Nano Lett. Vol. 10 (2010), p. 751 [18] H. Liu, J. Q. Xue, N. N. B. Cao: Langmuir Vol. 25 (2009), p. 12006 [19] Y. K. Wang, F. A. J. Dong: Biosens. Bioelectron. Vol. 21 (2005), p.
Another kind of label-free amperometric immunosensors places the redox species on an electrode surface, which eliminates direct contact with antibodies [8-11]. However, these systems faced the problems of complicated synthetic process [8] and limited sensitivities [9]. Therefore, more convenient and sensitive amperometric immunosensor methods need to be developed. Graphene sheet (GS), a one-atom thick sheet of sp2-bonded carbon atoms, has attracted intense interest ever since its discovery in 2004 [12].
Vol. 39 (2010), 228 [15] Y. Shao, J. Wang, H. Wu, J. Liu, I. Aksay and Y. Lin: Electroanalysis Vol. 22 (2010), p. 1027 [16] W. Yang, K. Ratinac, S. Ringer, P. Thordarson, J. Gooding and F. Braet: Angew. Chem. Int. Ed. Vol. 49 (2010), p. 2114 [17] M. Dresselhau, A. Jorio, M. Hofmann, G. Dresselhaus and R. Saito: Nano Lett. Vol. 10 (2010), p. 751 [18] H. Liu, J. Q. Xue, N. N. B. Cao: Langmuir Vol. 25 (2009), p. 12006 [19] Y. K. Wang, F. A. J. Dong: Biosens. Bioelectron. Vol. 21 (2005), p. P. F. Peng, P.